Silica Precipitation In Acidic Solutions: Mechanism, Ph Effect, And
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This study is the first to show that silica precipitation under very acidic conditions ([HCl] = 2−8 M) proceeds through two distinct steps. First, the monomeric form of silica is quickly depleted from
Aggregation kinetics and shear rheology of aqueous silica
However, the biochemical mechanisms involved in the transformation of silicic acid to solid siliceous materials are still poorly understood. Evidently, condensation of silicic acid in the
Precipitated Silica In subject area: Engineering Precipitated silica is defined as an amorphous form of silicon dioxide produced by reacting sodium silicate with sulfuric acid or a mixture of
Niny Z. Rao and, Lev D. Gelb. Molecular Dynamics Simulations of the Polymerization of Aqueous Silicic Acid and Analysis of the Effects of Concentration on Silica Polymorph Distributions, [4] E.A. Gorrepati, P. Wongthahan, S. Raha, H. S. Fogler, Silica precipitation in acidic solutions: Mechanism, pH effect, and salt effect, Langmuir, 26, pp 10467-10474, 2010 [5] X. Chen, M.
Moreover, the structure and distribution of these species are greatly dependent upon many parameters, such as solute concentrations, silica to alkali ratio, pH, and The result of this research shows that the process of silica scaling formation at the surface facilities of Dieng Geothermal Field is controlled by temperature and pressure and pH solution To compare the effect of Fe (III) on the polymerization of silicic acid and precipitation of silica, the change in Si-T, Si-M, Si- P < 0.45 µm, Fe-R, and Fe-T concentrations
A review on solubility and polymerization of silica
Article “Silica Precipitation in Acidic Solutions: Mechanism, pH Effect, and Salt Effect” Detailed information of the J-GLOBAL is a service based on the concept of Linking, Expanding, and
pH has a vast array of impacts from acid dissociation to mechanism change. Researchers in the field of geoscience have identified several effects on the stability of the
In order to investigate dissolution-precipitation behaviour of Mg-silicates and silica in slightly more acidic solution (pH = 5), L2, a mixture of different Mg-silicates was dissolved in Here, we show a pH-dependent stimulatory effect of such polyamines on silica polymerization. Notably, this process is decoupled from
In this study, we performed silica precipitation experiments with the cyanobacteria Calothrix sp. to investigate the mechanisms of silica biomineralization. Batch silica precipitation
A review of advances on solubility of amorphous silica in aqueous solutions has been made. Relevant literature on effects of temperature, pH, pressure and dissolved salt
Influence of pH, Temperature and Sample Size on Natural and
A general mechanism for the dissolution of minerals in non-oxidizing solutions was proposed by Crundwell (2014). This mechanism accounts for the effect of the potential Thus, the objective of this work is to clarify the behavior of Si in HCl solution, and to identify a viable approach for the desilication of Ti-bearing acid solution. The effects of acid The simulated dissolution rate agrees well with the value predicted by empirical model. By tracing hydrogen atoms, we found that the dehydroxylated silica surfaces in alkaline
The pH Cycling Before the remineralization pH cycling model, [16] the enamel specimens had another one-third of its surface covered with two layers of nail varnish (Risque) as a reference
The silica (SiO 2) particle was synthesized using the precipitation method of sodium silicate (Na 2 SiO 3) precursor by additional HCl as precipitant. In this paper, the precipitant
The production of silica is performed by mixing an inorganic, silicate-based precursor and an acid. Monomeric silicic acid forms and polymerizes to amorphous silica A better understanding of silica dissolution–precipitation reactions at high pH aqueous solutions allows for promotion of favorable (e.g., pozzolanic) reactions and mitigation 1. Introduction The dissolution of silica in NaOH solutions was undertaken in order to apprehend the experimental conditions allowing preparing a silicate solution. The latter is
Reducing the solution pH below 8.5, SNP can be stabilized in higher salinity in the presence of PA. The obtained results contribute to a better fundamental understanding of the Abstract This study describes a strategy to economically synthesize silica with high purity. For economical synthesis, it is critical to choose proper synthetic process and raw
This study is the first to show that silica precipitation under very acidic conditions ( [HCl] = 2-8 M) proceeds through two distinct steps. First, the monomeric form of silica is quickly depleted from The increase in amorphous silica content relative to crystalline content in silica-rich shales is attributed to the dissolution of clays and the resulting precipitation of amorphous silica
Gelation, Fragmentation and Reorganization of Precipitated Silica
In the current research, the gelation point of the silica gels and the rheological properties of the system were investigated. The gelation process of the silica gels was studied Results show that external factors such as elevated temperature and alkaline pH-values accelerate the dissolution, acidic pH, high salinities, and high initial silica concentrations Elizabeth A. Gorrepati et al., Silica precipitation in acidic solutions: Mechanism, pH effect, and salt effect, Langmuir, Vol. 26, No. 13, (2010), 10467–10474.
The behavior of sodium silicate solutions in an alkaline medium has been studied in the 11.56–9 pH range by adding different amount of hydrochloric acid into a concentrated To enhance the surface hydrophobicity and emulsification capacity of silica colloidal particles, a natural surface modification of soy hull polysaccharides (SHP) was
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