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1,2,4,5-Tetrazine – Tetrazine Bedeutung

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Abstract The synthesis and properties of several new energetic 1,2,4,5-tetrazine derivatives are described. These include energetic salts of 3,6-dihydrazino-1,2,4,5-tetrazine and several symmetrically and unsymmetrically substituted tetrazines with energetic substituents, in addition to a new nitro-tetrazine. 「3,6-Di-2-pyridyl-1,2,4,5-tetrazine, 96%」。富士フイルム和光純薬株式会社は、試験研究用試薬・抗体の製造販売および各種受託サービスを行っています。先端技術の研究から、ライフサイエンス関連、有機合成用や環境測定用試薬まで、幅広い分野で多種多様なニーズに応えています。 Donor-substituted alkynes, alkenes, donor-substituted and unsubstituted cycloalkenes, ketene acetals and aminals, as well as several cyclic enol ethers were used as dienophiles in these investigations. A number of 4-mono- and 4,5-disubstituted pyridazines

[290-96-0] C 2 H 2 N 4 (MW 82.07) InChI = 1S/C2H2N4/c1-3-5-2-6-4-1/h1-2H InChIKey = HTJMXYRLEDBSLT-UHFFFAOYSA-N ( [4+2] cycloaddition, azadiene, and pyridazine) Alternative Names: s -tetrazine, sym -tetrazine. Physical Data: mp 99 °C. 2 Solubility: sol most organic solvents. Form Supplied in: bright red crystals. Analysis of Reagent Purity: 1

1,2,4,5-Tetrazine derivatives as components and precursors of photo ...

Les 1,2,4,5-tétrazines sont très connues, ainsi que leurs nombreux dérivés 3,6-disubstitutés. Le composé 3,6-di-2-pyridyl-1,2,4,5-tétrazine 1 possède deux substituant pyridines (azines) et est un réactif important dans les réactions de type Diels-Alder. Il réagit avec le norbornadiène par une réaction de Diels-Alder suivie de deux réactions de rétro-Diels-Alder pour donner une

3,6-Diphenyl-1,2,4,5-tetrazine 6830-78-0

One of the successful strategies for the design of promising new energetic materials is the incorporation of both fuel and oxidizer moieties into the same molecule. Therefore, during recent years, synthesis of various nitro-azole derivatives, as compounds with a more balanced oxygen content, has become very

ChemicalBook 为您提供1,2,4,5-Tetrazine, 3-bromo- (2396594-00-4)的化学性质，熔点，沸点，密度，分子式，分子量，物理性质，毒性，结构式，海关编码等信息，同时您还可以浏览1,2,4,5-Tetrazine, 3-bromo- (2396594-00-4)产品的价格，供应商，贸易商，生产企业和生产厂家，最后1,2,4,5-Tetrazine, 3-bromo- (2396594-00-4)的中文

Symbols used in this document: AE Appearance energy AE Appearance energy Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific

IUPAC Standard InChIKey: DGLYTMLIGRQDPE-UHFFFAOYSA-N Copy Sheet of paper on top of another sheet CAS Registry Number: 1558-23-2 Chemical structure: This structure is also available as a 2d Mol file Other names: s-Tetrazine, 3,6-dimethyl-; Dimethyl-s-tetrazine Permanent link for this species. Use this link for bookmarking this species for future reference.

  • Azido and Tetrazolo 1,2,4,5‐Tetrazine N‐Oxides
  • Recent Advances and Applications in 1,2,4,5-Tetrazine Chemistry
  • 1,2,4,5-Tetrazine, 3-chloro- CAS#: 1185108-36-4
  • 1,2,4,5-Tetrazine, 3-methyl-6-phenyl-

A series of framework coordination polymers reveals the use of 1,2,4,5-tetrazines as efficient bridging ligands towards silver(i) and copper(i) ions. All four nitrogen atoms were functional as lone pair donors leading to an unprecedented mu(4)-coordination of the ligands (1,2,4,5-tetrazine, ttz; 3,6 ChemicalBook 为您提供1,2,4,5-Tetrazine, 3-hydrazinyl- (79329-78-5)的化学性质，熔点，沸点，密度，分子式，分子量，物理性质，毒性，结构式，海关编码等信息，同时您还可以浏览1,2,4,5-Tetrazine, 3-hydrazinyl- (79329-78-5)产品的价格，供应商，贸易商，生产企业和生产厂家，最后1,2,4,5-Tetrazine, 3-hydrazinyl- (79329-78-5)的 Substituted tetrazines have been found to undergo facile inverse electron demand Diels–Alder reactions with “tunable” reaction rates.

A very high heat of formation is displayed by the title compound 1, the first azo-1,2,4,5-tetrazine to be synthesized and likely the most dense C,H,N molecule known. These properties make 1 a suitabl

1,2,4,5-Tetrazine, 3,6-dimethyl-

1,2,4,5-Tetrazine derivatives as components and precursors of photo ...

Download Citation | Recent Advances and Applications in 1,2,4,5-Tetrazine Chemistry | This review focuses on the chemistry of 1,2,4,5-tetrazine and its derivatives in the last 10 years for the ChemicalBook 致力于为化学行业用户提供1,2,4,5-Tetrazine, 3-bromo-的性质、化学式、分子式、比重、密度,同时也包括1,2,4,5-Tetrazine, 3-bromo-的沸点、熔点、MSDS、用途、作用、毒性、价格、生产厂家、用途、上游原料、下游产品等信息。

1,2,4,5-Tetrazine derivatives are of considerable interest because of their unique role in constructing diverse aza-containing heterocycles. 1 Moreover, they exhibit versatile applications in coordination chemistry, 2 protein and live cell labeling, 3 and as raw materials or intermediates for the manufacture of organic solar cells,4 high energetic materials, 5 and Considerable recent attention has been focused on research and development of high-nitrogen energetic materials. Among polynitrogen energetic materials, 1,2,4,5-tetrazine derivatives are of particular interest owing to their high density, thermostability, and

Although H-Tet was used earlier for the development of fluorogenic tetrazine-functionalized fluorophores, the majority of the commercially available tetrazine-functionalized fluorophores exhibiting FRET behavior are conjugated with 3-methyl-6-phenyl-1,2,4,5-tetrazine (Me-Tet) derivatives. Uses 3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu (II) complexes, via metal-assisted hydrolysis. It also may be used in the synthesis of novel cyclic tetranuclear ZnII complex and synthesis of substituted 3,6-di (2-pyridyl)pyridazines, via inverse electron demand Diels Alder Thomas Geiger, Simon Schundelmeier, Thorsten Hummel, Markus Ströbele, Wolfgang Leis, Michael Seitz, Clemens Zeiser, Luca Moretti, Margherita Maiuri, Giulio Cerullo, Katharina Broch, Jörn Vahland, Karl Leo, Cäcilia Maichle‐Mössmer, Bernd Speiser, Holger F. Bettinger. Modulating the Electronic and Solid‐State Structure of Organic Semiconductors by Site‐Specific

Intermediate 3,6-diphenyl-1,4-dihydro-1,2,4,5-tetrazene is in turn prepared by refluxing elemental sulfur, benzonitrile (1.5 equiv), and hydrazine monohydrate (3 equiv) in ethanol (eq 15) 17 b Purification: recrystallization from CHCl 3 or column chromatography (silica gel, hexanes/EtOAc, 4:1) yields red purple needles. A series of nitrogen-rich “green” Energetic Materials (EMs), some with improved sensitivity, thermostability, and very low toxicity, were synthesized on the basis of 3,5-diamino-1,2,4-triazole (DAT) and 1,2,4,5-tetrazine building blocks. Since DAT contains several nucleophilic reactive sites, obtaining selective reactivity and specific isomeric products with 1,2,4,5-tetrazine The VUV electronic absorption spectrum of 1,2,4,5-tetrazine has been re-investigated, and together with electron energy-loss spectra has led to identi

A series of framework coordination polymers reveals the use of 1,2,4,5-tetrazines as efficient bridging ligands towards silver(i) and copper(i) ions. All four nitrogen atoms were functional as lone pair donors leading to an unprecedented μ4-coordination of the ligands (1,2,4,5-tetrazine, ttz; 3,6-dimethyl-1,2,4,5-t 结构: 1,2,4,5-四嗪的结构特点是六元环上分别在1、2、4和5位上有四个氮原子，其他位置为碳原子。 该结构赋予它独特的化学性质，尤其是在与某些双烯体（dienophiles）的反应中表现出高活性。 1,2,4,5-Tetrazine, 3,6-diphenyl- Formula: C 14 H 10 N 4 Molecular weight: 234.2560 IUPAC Standard InChI: InChI=1S/C14H10N4/c1-3-7-11 (8-4-1)13-15-17-14 (18-16-13)12-9-5-2-6-10-12/h1-10H Copy

The oxidation products of 3,6-diazido-1,2,4,5-tetrazine (1) and 6-amino- [1,5- b]tetrazolo-1,2,4,5-tetrazine (2) have been characterized. 3,6-Diazido-1,2,4,5-tetrazine-1,4-dioxide (see picture) was produced by oxidation of 1 with peroxytrifluoroacetic acid, and more effectively using hypofluorous acid, and 2 can be oxidized to its mono- and di-N-oxide. These products

3,6-Diphenyl-1,2,4,5-tetrazine

Aldrich-792594; 3,6-Dichloro-1,2,4,5-tetrazine 0.96; Synonyms: Dichloro-s-tetrazine; Linear Formula: C2Cl2N4; Empirical Formula: C2Cl2N4; find related products

3,6-Diphenyl-1,2,4,5-tetrazine † This is not the most recent version, view other versions Dale L. Boger, Minsheng Zhang

推荐产品 产品名称：3,6-Dimethyl-1,2,4,5-tetrazine纯度：98% 产品编号：1583651 CAS号：1558-23-2 ￥ ŴƦƀƎƦƦ /100mg ￥ ɅƙƦƎƦƦ /250mg ￥ ȬNJNJƦƎƦƦ /1g ￥ ƙȬȬƦƎƦƦ /5g 现货 基本信息 属性 计算化学 产品编号 2150627 CAS 号 2920396-12-7 ChemicalBook 致力于为化学行业用户提供1,2,4,5-Tetrazine, 3-chloro-的性质、化学式、分子式、比重、密度,同时也包括1,2,4,5-Tetrazine, 3-chloro-的沸点、熔点、MSDS、用途、作用、毒性、价格、生产厂家、用途、上游原料、下游产品等信息。 Besides chlorotetrazines, bromotetrazines are also widely used to synthesize tetrazine derivatives. The Wombacher group 59 used 3-bromo-6-methyl